Orbiting Resonances and Bound States in Molecular Scattering

A family of orbiting resonances in molecular scattering is globally described by using a single pole moving in the complex angular momentum plane. The extrapolation of this pole at negative energies gives the location of the bound states. Then a single pole trajectory, that connects a rotational band of bound states and orbiting resonances, is obtained. These complex angular momentum singularities are derived through a geometrical theory of the orbiting. The downward crossing of the phase–shifts through π/2, due to the repulsive region of the molecular potential, is estimated by using a simple hard–core model. Some remarks about the difference between diffracted rays and orbiting are also given.